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Bernhard Neumann.

The theory and practice of electrolytic methods of analysis

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lead-antimony, 230
lead-tin, 228
lead-tin-bismuth, 229
lead - tin - bismuth - cadmium,

229

tin-antimony-arsenic, 230
tin-mercury, 230
tin-zinc, 228
Aluminium,

Separation from cobalt, 218
from copper, 177
from iron, 213
from nickel, 218
from zinc, 218
Aluminium bronze, analysis of,

228

Amalgams, 160
Ampere, definition, 20
Ampere meters ; or ammeters, 57
Anions, definition of, 5, 9
Anodes, definition of, 5



Antimony, electrolytic deposition
of, 144

Separation from arsenic, 200
from cadmium, 208
from copper, 186
from gold, 199
from mercury, 194
from silver, 191
from. tin, 201
Antimony, amalgam, 164
Arsenic, electrolytic deposition of,
148

Separation from antimony,
200

from bismuth, 200
from cadmium, 208
from copper, 185
from gold, 198
from lead, 189
from mercury, 194
from platinum, 199
from silver, 191



BASINS, for electrolytic operations,

80

Bismuth, electrolytic deposition
of, 157

Separation from arsenic, 200
from cadmium, 200
from cobalt, 200
from copper, 185
from iron, 200
from lead, 188
from mercury, 194
from nickel, 200
from silver 191



250



SUBJECT INDEX



Bismuth, separation from tin,
200

from zinc, 200

Bismuth amalgam, 162

Brass, analysis of, 220

Britannia metal, analysis of,
231

Bronze, analysis of, 226

aluminium, analysis of, 228
phosphor, analysis of, 227

Burnt pyrites, analysis of, 242



CADMIUM, electrolytic deposition
of, 122

Separation from alkalies, 208
from arsenic 208
from bismuth, 200
from chromium, 208
from cobalt, 206
from copper, 174
from iron, 207
from lead, 190
from manganese, 208
from mercury, 196
from molybdenum, 208
from nickel, 206
from osmium, 208
from silver, 192
from tin, 208
from tungsten, 208
from zinc, 205
Cadmium amalgam, 161
Charges of the ions, 19, 20, 23
China silver, analysis of, 225
Cobalt, electrolytic deposition of,
111

Separation from aluminum,
218

from bismuth, 200
from cadmium, 206
from chromium, 218
from copper, 172
from iron, 209
from lead, 190
from manganese, 217
from mercury, 196
from nickel, 214
from silver, 192
from zinc, 215
Cobalt, ores of, analysis, 241



Cobalt, regulus, analysis, 241
Cobalt smelting products, analysis,

241

Complex salts, 10, 11
Conductivity of the electrolyte,
9, 21, 72

of water, 8, 31
maximum, 27, 28

molecular, 27
relative, 28
specific, 27

Copper, electrolytic deposition of,
92

Separation from aluminium,
177

from antimony, 186
from arsenic, 185
from barium, 177
from bismuth, 185
from cadmium, 174
from chromium, 177
from cobalt, 172
from iron, 169
from lead, 177
from magnesium, 177
from manganese, 179
from mercury, 184
from nickel, 172
from potassium, 177
from silver, 181
from tin, 186
from zinc, 167

Copper ashes, analysis of, 242
Copper, black, analysis of, 236
Copper, German mint, analysis of,

227

Copper matte, analysis of, 242
Copper pyrites, 242
Copper, raw, analysis of, 236
Copper, refined, analysis of, 237
Copper regulus, analysis of, 241
Copper slag, analysis of, 242
Copper voltameter, 52
Coulomb, definition of, 20
Coupling cells and accumulators,
mixed, 68
parallel, 66
series, 66

Cupriferous flue dust, analysis of,
242
pyrites, analysis of, 242



UNIVERSITY



SUBJECT INDEX



251



Current conduction, 67

regulation, 49, 63, 87
Current density, calculation of, 38,
86

definition of, 37

normal, 37, 87

influence upon deposits, 38
Current strength, diminution of, 74

increase of, 65

measurement of, 50, 60, 87

unit of, 20



DECOMPOSITION of acetic acid, 14
formic acid, 13
lead chloride, 6, 34
potassium sulphate, 8, 34
typical complex salts, 12, 13
zinc chloride, 6, 39, 41

Decompositions, primary, 6
secondary, 8, 11

Decomposition values, 45, 46

Deposits, drying the, 89
washing the, 89

Detonating gas voltameter, 52, 53

Dissociation, theory of, 22, 23, 25
of water, 24, 31, 39

Double salts, 10, 11



ELECTEOCHEMISTKY, development

of, 1

Electrochemical equivalents, 19
Electrodes, basin, 80
fork-shaped, 108
forms of, 80, 81, 82
holders for, 84, 85
jacket, 83
materials for, 79
saucer, 82
spiral, 83

Electrolysis, conduct of analytic,
86

phenomena of, 6, 33
Electrolytes, conductivity of, 21,
72,88

constitution of, 21
Electrolytic procedure, general re-
marks, 79, 86

Electro-motive force, calculation
of, 46



Electro-motive force, influence upon

decompositions, 36
measurement of, 60, 61, 63,

87

Electrotyping, earliest examples
of, 1



FAHL ores, analysis of, 244
Faraday's laws, 16, 17
Flue dust, analysis of, 242



GALENA, analysis of, 242
Galvanometers, general remarks,
50

tangent, 54
torsion, 56

Gas couple, example of, 44
German silver, analysis of, 222
Gold, analysis of mint-, 228

electrolytic deposition of,

152

separation from silver, 191
mercury, 195
other metals, 198



HAFTINTENSITAT, Le Blanc's theory
of, 44



IONS, absolute velocity of, 29
definitions of, 5, 9
electro-static charges of, 19,

20,23

energy carried by, 19, 20, 23,
migration of, 24
relative velocities of, 25, 26,

29

valency of, 9, 23
Ionic dissociation, 31
Ionic reactions, 10
Iridium, electrolytic deposition of,

156

Iron, electrolytic deposition of,
102

separation from aluminium,
213

from bismuth, 200
from cadmium, 207



252



SUBJECT INDEX



Iron, separation from chromium, i
214

from cobalt, 209

from copper, 169

from gold, 198

from lead, 190

from manganese, 211

from mercury, 196

from nickel, 209

from silver, 192

from zinc, 211
Iron, analysis of cast, 238
analysis of ores of, 238



JACKET electrodes, 83
Joule, definition of, 20



KATHODES, definition, 5
Kations, definitions of, 5, 9
Kohlrausch's laws, 28



LEAD amalgam, 161
Lead, electrolytic deposition of,
126

separation from arsenic, 189
from bismuth, 188
from cadmium, 190
from cobalt, 190
from copper, 177
from iron, 190
from manganese, 189
from mercury, 188
from nickel, 190
from silver, 187
from zinc, 190
Lead trees, 42

Lead, argentiferous, analysis of,
234

hard, analysis of, 230
matte, analysis of, 241
refined, analysis of, 232
soft, analysis of, 232



MANGANESE, electrolytic deposition
of, 130

separation from cadmium,
208



Manganese, separation from cobalt,
217

from copper, 179
from iron, 211
from lead, 189
from mercury, 196
from nickel, 217
from zinc, 218

Mercury, electrolytic deposition of,
138

separation from antimony,
194

from arsenic, 194
from bismuth, 194
from cadmium, 196
from cobalt, 196
from copper, 184
from gold, 195
from iron, 196
from lead, 188
from manganese, 196
from nickel, 196
from osmium, 196
from palladium, 196
from platinum, 196
from silver, 191
from tin, 195
from zinc, 196
Metals incapable of deposition,

list of, 159
Migration of the ions, theory of,

24
Migration velocities, absolute, 29

relative, 25, 26, 29
Mixed coupling, 68
Mixed salt solutions, decomposition
of, 35



NICKEL, electrolytic deposition of,
106

separation from aluminium,
218

from bismuth, 200
from cadmium, 206
from chromium, 218
from cobalt, 214
from copper, 172
from iron, 209
from lead, 190
from manganese, 217



SUBJECT INDEX



253



Nickel, separation from mercury,
196

from silver, 192
from zinc, 215

Nickel, cube-, analysis of, 239
mint-, analysis of, 222
mint-, old Swiss, analysis of,

225

ores, analysis of, 241
raw, analysis of, 239
smelting products, analysis of,

241

Speiss, analysis of, 239
Normal current density, definition
of, 37



OHM, definition of, 20

Organic acids, decomposition of,

13, 14
Osmotic pressure, law of, 30



PALLADIUM, electrolytic deposition

of, 155

Parallel coupling, definition of, 67
Peroxide formation, conditions of,

42

Phosphor-bronze, analysis of, 227
Platinum, electrolytic deposition

of, 154

separations from other metals,

199

Polarisation, causes of, 48
Products of electrolysis, primary,

33, 35

secondary, 33, 35
Pyrites, analysis of roasted, 242



REACTIONS, ionic, 10
primary, 6, 8
secondary, 8. 11
Kegulating the current, 63, 87
Eesistance, definition of circuit, 67
Resistance of metallic conductors,

67, 72, 74

Resistance-boxes, general remarks,
74,75

with mercury contacts, 76
with plug contacts, 75



Eesistances, forms of adjustable

wire, 77, 78
Eesults of electrolysis, recording

the, 90
Ehodium, electrolytic deposition

of, 156
Eose's metal, analysis of, 229



SALT solutions, decomposition of

mixed, 35

Salts, complex, 10, 11
double, 10, 11
metallic, percentage of metals

in, 246
Secondary cells or batteries, use

of, 69
Separations of several metals,

methods used, 165, 219
Separations in acid solutions, 40

by varying E.M.F., 37
Series coupling, definition of, 66
Shunt circuit, definition of, 55

use of, 57

Silver, electrolytic deposition of,
134

separation from antimony, 191
from arsenic, 191
from bismuth, 191
from cadmium, 192
from cobalt, 192
from copper, 181
from gold, 191
from iron, 192
from lead, 187
from mercury, 191
from nickel, 192
from palladium, 192
from platinum, 192
from zinc, 192

Silver, China, analysis of, 225
German, analysis of, 222
leaf, analysis of counterfeit,

228

mint-, analysis of, 221
Silver tree, formation of, 42
Silver voltameter, 51
Solder, analysis of, 228
Spongy deposits, cause of, 41
Steel, analysis of, 238
Stibnite, analysis of, 244



254



SUBJECT INDEX



Supports for electrodes, 84, 85
Switch-board for cells and accumu-
lators, 69



TANGENT galvanometer, 54
Temperature, influence of, 88
Tetrahedrite, analysis of, 244
Thallium, electrolytic deposition

of, 157

Thermo-battery, use of, 71
Tin, electrolytic deposition of, 148
separation from antimony, 201
from bismuth, 200
from cadmium, 208
from copper, 186
from gold, 198
from mercury, 195
Tin amalgam, analysis of, 230
Tin, commercial, analysis of, 238
Tin-foil, analysis of, 238
Tin-stone, analysis of, 244
Tombac, analysis of, 220
Torsion galvanometer, 56
Tree formations, cause of, 42
Type metal, analysis of, 230



VOLT, definition of, 20



Voltaic series of metals, 35
Voltameters, general remarks, 50

copper, 52

detonating gas, 52, 53

silver, 51
Voltmeters, technical forms, 62, 63



WOOD'S metal, analysis of, 229



ZINC, electrolytic deposition of,
113

separation from aluminium,
218

from bismuth, 200
from cadmium, 205
from chromium, 218
from cobalt, 215
from copper, 167
from gold, 198
from iron, 211
from lead, 190
from manganese, 218
from mercury, 196
from nickel, 215
from silver, 192

Zinc amalgam, 160

Zinc, analysis of commercial, 234




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56 Illustrations. 2s. Gd.

By SYDNEY P. WALKER, M.I.E.E., M.I.M.E., A.M.I.C.E.;

ELECTRICITY IN OUR HOMES AND WORKSHOPS. A

Practical Treatise on Auxiliary Electrical Apparatus. Third Edition. Revised
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' It would be difficult to find a more painstaking writer when he is describing the


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